How Does a Phone Battery Work?: How a lithium-ion battery stores and releases energy

CHEMISTRY · 4 MIN

How does a flat little pouch keep your phone alive all day?

No chemistry class needed. We'll open a phone, slice its battery into layers thinner than a hair, then shrink down to watch the tiny lithium shuttle that runs every time you scroll.

8 steps · 8 quick challenges

Step 1 of 8 · Your phone

A day of power in your pocket

A phone on a desk, plugged in to charge. Everything it does, from the screen to the camera, runs on the flat pack hidden inside.

Your phone runs on stored energy. A lithium-ion battery keeps that energy locked in chemistry, and lets it out as electricity whenever the phone asks for it.

  1. Energy to spend. Every swipe, photo and video call uses energy. The screen glows, the chips think and the radio talks to the nearest tower. None of that energy is made on the spot. It was packed into the battery earlier, while the phone was charging, and now it's being spent little by little, all day long, until you plug in again. Like a packed lunch: made in the morning, eaten bit by bit.

    A typical phone battery stores about 15 to 20 watt-hours of energy. That's enough to light a 10-watt bulb for about two hours, but a careful phone can stretch it over a whole day.

    The biggest energy users are the screen and the radios. Bright screens, weak signal and video calls all drain the battery faster than reading text.

    Phones also sip power while they sleep. Checking for messages and keeping time uses tiny amounts, which is why a phone left alone for a week will still slowly run flat.

  2. Electricity is moving electrons. Electrons are tiny specks of electric charge found in every atom. Electricity is just electrons flowing along a wire. To power a phone, the battery has to push electrons out of one end, through the phone's circuits, and back into its other end. Those two ends of the battery are called minus (−) and plus (+). Like water flowing round a loop of pipe and turning a water wheel on the way.

    Electrons are far too small to see. Even a thin wire carrying a small current has billions of billions of them drifting along each second.

    Electrons only flow if there's a full loop, called a circuit. Break the loop anywhere and the flow stops, which is how a switch works.

    The charging cable is part of a loop too. While charging, the charger pushes electrons into the battery's minus end, the opposite way to normal use.

  3. Chemistry, not a tank. A battery isn't a tank full of electricity. It stores energy in chemistry: in where certain atoms sit. When lithium atoms move from one material to another, they release energy, and the battery turns that into a push on electrons. Charging simply moves the lithium back again, ready to be spent once more. Like a ball at the top of a slide: the energy is in where it sits.

    Lithium is the lightest metal there is. Being light and very eager to give up an electron makes it brilliant for packing lots of energy into a small, light battery.

    The 'ion' in lithium-ion means a charged atom. We'll meet lithium ions properly once we shrink down to the size of atoms.

    Because the same lithium is moved back and forth, the battery can be charged hundreds of times. Older one-use batteries burned their chemicals up once and were done.

Energy stored
≈ 17 Wh
First sold
1991

Did you know? The lithium-ion battery won the 2019 Nobel Prize in Chemistry. John Goodenough, one of the three winners, was 97, the oldest Nobel winner ever.

Read more

Almost every gadget you own runs on a lithium-ion battery: phones, laptops, earbuds, watches, electric toothbrushes, scooters and electric cars.

They all work the same way. Inside, two different materials are separated by a thin wall soaked in liquid. Lithium moves through the liquid from one material to the other and back again.

Sony sold the first lithium-ion batteries in 1991, in a video camera. Before that, rechargeable batteries were heavier and held much less energy, so phones were the size of bricks.

In the rest of this story, we'll open the phone, slice into the battery, and shrink down until we can watch single lithium atoms make the trip.

A full phone battery holds about as much energy as a single bite of chocolate, but it can run a tiny computer all day.

Step 2 of 8 · Your phone

A flat, sealed pouch

Let's open the phone up. Lift away the screen and almost everything underneath is one thing: the battery.

Under the screen, the battery takes up most of the space. It's a soft, sealed pouch with two metal tabs and a tiny guard chip keeping watch.

  1. The pouch. Phone batteries are thin pouches of foil-covered plastic, sealed shut all round the edges. Inside, very thin layers are folded and stacked, soaked in a liquid. The seal matters: air and water must never get in, because they react with lithium and spoil the battery. A flat pouch also uses every bit of space. Like a vacuum-sealed packet of coffee, but full of layers.

    The pouch wall is a sandwich itself: plastic on the outside, a thin aluminium foil in the middle to block water and air, and another plastic on the inside that melts to make the seal.

    Pouches are light and can be made almost any flat shape, which is why phones moved to them. Laptops and electric cars often use metal cans instead.

    If a battery is damaged or very old, gas can build up inside. The pouch then puffs up like a pillow. A swollen battery should be replaced, never pressed or punctured.

  2. Two tabs. Two small metal strips poke out of one edge. These are the battery's minus (−) and plus (+) ends, called terminals. Inside the pouch, each tab is welded to a stack of thin metal foils. Outside, they connect to the phone's circuits. Every electron the phone uses leaves through one tab and comes home through the other. Like the two ends of a garden hose: one out, one back in.

    The minus tab is usually nickel or nickel-coated copper, and the plus tab is aluminium. Each one matches the foil it's welded to inside.

    The tabs carry all the current the phone draws, up to a few amps when it's busy. That's why they're thicker and wider than the paper-thin foils they gather up.

    A phone battery is just one cell. Laptops and electric cars join many cells together, tab to tab, to get more power and more energy.

  3. The guard chip. Right beside the tabs sits a little circuit board with a guard chip on it. It watches the battery all the time: how full it is, how hot it is, and how much current is flowing. If anything goes wrong, like charging too far or a short, it switches the battery off in a split second to keep you and the phone safe. Like a lifeguard watching the pool, ready to blow the whistle.

    The guard chip stops charging at about 4.2 to 4.4 volts and stops draining at about 3 volts. Going past either limit damages the battery from inside.

    It also counts how much charge goes in and out. That's how your phone can show an exact percentage instead of just 'full' or 'empty'.

    There's a temperature sensor too. If the battery gets too hot, the phone slows charging or stops altogether and shows a warning.

Share of phone
≈ ⅓ of space
Thickness
≈ 5 mm

Did you know? When a phone battery swells, it's gas from slowly breaking-down liquid inside. Some phones' screens get pushed right off their frames by a puffed-up pouch.

Read more

A phone battery is the single biggest part inside a phone. Designers build the rest of the phone around it.

Batteries are sealed shut because the lithium inside reacts with water. Even the moisture in a breath of air would slowly spoil it.

The guard chip is part of the battery itself, not the phone. Every lithium-ion battery sold for phones and laptops has one, because these batteries hold a lot of energy in a small space.

Next, we'll slice through the pouch and look at the layers hidden inside.

The guard chip checks the battery thousands of times every second, for the whole life of your phone.

Step 3 of 8 · Inside the pouch

Two sides, many layers

Slice through the pouch and look at the cut edge. It's not one block, but a stack of layers, each thinner than a hair.

The battery is a stack of two kinds of layer: grey graphite on copper (the minus side) and a metal oxide on aluminium (the plus side), repeated again and again.

  1. The minus side. The grey layers are graphite, the same stuff as pencil 'lead', spread on a thin copper foil. This is the battery's minus side, called the anode. When the battery is charged, this is where the lithium waits. The thin copper foil gathers electrons from the graphite and carries them out to the minus tab. Like a car park, where the lithium waits for its trip.

    Graphite is made of pure carbon. Its atoms sit in flat sheets stacked on top of each other, with gaps just the right size for lithium to slip into.

    The copper foil is about 6 to 10 thousandths of a millimetre thick, roughly ten times thinner than a human hair.

    Copper is used because it carries electricity very well and doesn't react with lithium at the minus side's low voltage.

  2. The plus side. The darker layers are a metal oxide: metal atoms like cobalt, held together by oxygen. It's spread on aluminium foil. This is the plus side, called the cathode. When the battery is empty, the lithium has moved here. The oxide pulls on lithium much harder than graphite does, and that pull is where the energy comes from. Like the bottom of a slide, where everything ends up.

    Most phone batteries use lithium cobalt oxide. Electric cars often use oxides with nickel and manganese, or a cheaper iron phosphate.

    Aluminium is used on this side because it's light, carries electricity well, and copper would slowly dissolve at the plus side's high voltage.

    John Goodenough found the cobalt oxide cathode in 1980. It roughly doubled the voltage of earlier lithium batteries, to almost 4 volts.

  3. Again and again. A single minus layer facing a single plus layer would only hold a tiny bit of energy. So the battery repeats them, minus, plus, minus, plus, dozens of times, folded or stacked inside the pouch. All the copper foils join one tab, and all the aluminium foils join the other. More layers means more energy. Like a book: lots of thin pages make a thick story.

    A phone battery has around 20 to 40 pairs of layers. Unfolded, the coated foils would cover an area about the size of a kitchen table.

    Thin layers matter because lithium only has to travel a short way. Thicker layers would hold more, but the battery would be slower to charge and give out power.

    Every gadget battery makes this same trade-off between packing in energy and giving it out fast.

Layer pairs
≈ 30
Foil
≈ 0.01 mm

Did you know? The copper and aluminium foils inside are thinner than a human hair. Some are thinner than kitchen cling film.

Read more

Every battery has two different materials, called electrodes. One pulls on lithium more weakly (graphite), and one pulls more strongly (the metal oxide). That difference is what stores energy.

The names minus and plus come from the electrons. Electrons leave the battery from the minus side and come back in at the plus side.

Akira Yoshino built the first practical lithium-ion battery in 1985 by pairing Goodenough's oxide with a carbon minus side. That pairing is still used in your phone today.

But if the two sides touch, the battery fails at once. So what's between them?

Lay all the layers inside a phone battery side by side and they'd cover a small table.

Step 4 of 8 · Inside the pouch

The wall between

Between every minus layer and plus layer sits one more thin sheet. It's the most important wall in the battery.

A thin plastic sheet full of tiny holes keeps the two sides apart. It's soaked in a liquid that lets lithium through, but blocks electrons.

  1. The separator. Between each minus and plus layer is a very thin plastic sheet called the separator. It's full of tiny holes, far too small to see, like a sponge. It keeps the two sides from ever touching. If they did touch, the energy would rush out all at once as heat, with nothing useful done. The sheet is thinner than a hair. Like a tennis net: it keeps the two sides apart but lets the ball through.

    Separators are usually made of polyethylene or polypropylene, the same plastics as shopping bags and food tubs, stretched until they're full of holes.

    A typical one is about 10 to 20 thousandths of a millimetre thick. About half of it is empty space.

    It has to be strong as well as thin. It must not tear while the layers are wound or stacked, or while they swell and shrink during charging.

  2. The electrolyte. The holes are filled with a liquid called the electrolyte, with lithium salt dissolved in it. It does a very special job: lithium ions can swim through it, but electrons can't. That one rule makes the battery work. Electrons are forced to take a different path, out through the tabs and your phone, to reach the other side. Like a footbridge only for walkers: cars must take the long road.

    The liquid isn't water. Water would split apart at the battery's voltage, so it's a carefully chosen mix of solvents that can handle about 4 volts.

    There's very little of it, just a few drops spread through all the layers. It soaks into the tiny holes in the separator and the electrodes.

    The liquid can burn if the battery overheats. That's one reason battery makers keep looking for solid electrolytes that won't catch fire.

  3. Why they must never touch. If the minus and plus layers touched, electrons could jump straight across without going through your phone. That's called a short circuit. All the stored energy would rush through one spot and turn into heat. So the separator has a safety trick: near 130 °C its plastic melts just enough to seal the holes and stop everything. Like a fire door that shuts itself when it gets too hot.

    This safety trick is called a shutdown. Once the holes close, lithium can't get through either, so the battery stops working before it gets hotter.

    A bent, crushed or punctured battery is dangerous because the layers might touch. That's why you should never pierce or squash one.

    Some separators have a thin ceramic coating too. Ceramic doesn't melt, so the wall keeps standing even if the plastic starts to soften.

Separator
≈ 0.015 mm
Shuts at
≈ 130 °C

Did you know? The holes in the separator are a few hundred times wider than a lithium ion, but far too small for even the tiniest speck of graphite to squeeze through.

Read more

Every battery needs something that lets the lithium through but blocks the electrons. Without it, the battery would empty itself straight away.

That's the clever part. Because the electrons can't take the short way through the liquid, the only way to reach the other side is the long way: through your phone.

This is also why a battery doesn't run flat sitting in a drawer. With no outside loop, the electrons have nowhere to go, so the lithium can't move much either.

Next, we'll shrink down much further, right into the gap between the layers, to see the atoms themselves.

The wall that keeps your phone safe is thinner than cling film and about half empty space.

Step 5 of 8 · The lithium shuttle

Meet lithium

We're between the layers now, a million times smaller. Graphite below, the metal oxide above, and liquid in between. Time to meet lithium.

Lithium atoms have one loose electron they give up easily. Without it, a lithium atom becomes a lithium ion, and it can tuck itself between the sheets of graphite.

  1. Atoms up close. Down here, everything is atoms. Below, graphite: carbon atoms joined in flat, honeycomb sheets, standing side by side like pages. Above, the metal oxide: cobalt atoms (blue) and oxygen atoms (red) in sheets of their own. Between them, the liquid. Both sides have gaps between their sheets, just wide enough for lithium. Like two bookshelves facing each other across a stream.

    Atoms are so small that about 10 million of them would fit across the full stop at the end of this sentence.

    In graphite, each carbon atom holds on tightly to three neighbours in its own sheet, but the sheets themselves only hold each other loosely.

    We've drawn the atoms as balls and sticks so you can see them. Real atoms are fuzzy clouds, with no hard edges.

  2. A loose electron. A lithium atom has three electrons, but one of them sits far out on its own and is very loosely held. Lithium gives it up easily. When it does, what's left has a plus charge, because it lost a minus. That's a lithium ion, written Li⁺. Lithium ions can move through the liquid, while the electron goes another way. Like a dandelion seed: one puff and it's off.

    An ion is any atom that has lost or gained electrons, so it carries an electric charge. The 'ion' in lithium-ion means these charged lithium atoms.

    Lithium gives up its electron more easily than almost any other atom. That's what makes the battery's voltage high.

    Lithium is also tiny and light, the third-lightest of all atoms, so a battery can hold a lot of it without being heavy.

  3. Parked between pages. When the battery is charged, the lithium sits tucked between the graphite sheets, about one lithium for every six carbon atoms. The sheets don't break or change. They just open up slightly to make room. This gentle slotting-in is called intercalation, and it's the secret to why a lithium-ion battery can be recharged so many times. Like bookmarks slipped between the pages of a book.

    Graphite swells by about a tenth when it's full of lithium, then shrinks back when the lithium leaves.

    Earlier batteries used pure lithium metal for the minus side. It grew sharp spikes when recharged and could catch fire. Parking lithium inside graphite fixed that.

    Stanley Whittingham first showed in the 1970s that lithium could slip in and out of layered materials this way. He shared the 2019 Nobel Prize for it.

Lithium
3 electrons
Graphite
1 Li : 6 C

Did you know? Pure lithium metal is so reactive it's stored under oil. Drop a piece in water and it fizzes and races around the surface.

Read more

Every atom has a tiny heavy centre with a plus charge, and electrons whizzing around it with a minus charge. Normally they balance out.

Lithium's third electron sits further from the centre than the other two, so the centre's pull on it is weak. That's why lithium lets go of it so easily.

Once a lithium atom loses that electron, it's about half the size and carries a plus charge. Now it's small enough to swim through the liquid and squeeze between sheets of atoms.

So a charged battery is graphite full of lithium. What happens when you switch your phone on?

Your phone battery holds roughly a thousand billion billion lithium atoms, all waiting to make the same short trip.

Step 6 of 8 · The lithium shuttle

Using your phone

You pick up your phone and the screen lights up. A loop opens from the battery through the phone, and the lithium starts to move.

Lithium ions leave the graphite, cross the liquid and settle into the oxide. Their electrons can't follow, so they run through your phone instead, powering it on the way.

  1. Ions swim across. As soon as there's a path for electrons, lithium starts leaving the graphite. Each lithium atom drops its loose electron and becomes an ion. The ion swims across the liquid and through the separator's holes to the oxide side, which pulls on lithium more strongly. That stronger pull is what drives the whole battery. Like a ball rolling downhill: it goes where the pull is strongest.

    The ions don't travel in a straight line. They bump and wander through the liquid, but overall they drift steadily from minus to plus.

    Each trip is only a few hundredths of a millimetre long, but every second billions of billions of ions make it.

    When lithium leaves graphite and settles into the oxide, energy is released. The battery hands that energy to the electrons, and they carry it out to the phone.

  2. Electrons take the wire. Remember: electrons can't cross the liquid. So each electron left behind takes the only path there is, out of the copper foil, through the minus tab, round your phone's circuits, and back in at the plus side. Along the way it does the work: lighting pixels and running chips. The push on each electron is the voltage, about 3.7 volts. Like a river turning a mill wheel on its way down the hill.

    Voltage is how hard the battery pushes each electron. A bigger difference between the two sides' pull on lithium means a bigger voltage.

    Current is how many electrons flow each second. A phone running a game draws more current than one showing the lock screen.

    Power is the two together: voltage times current. A busy phone uses around 2 to 5 watts, and the battery supplies it all.

  3. Meeting again. On the plus side, the lithium ion slips between the oxide's sheets. At the same moment, an electron arrives through the aluminium foil, having gone round the phone. The two meet up again in the oxide. Ion in through the liquid, electron in through the wire: the books stay balanced, and the battery keeps going. Like two friends taking different routes and meeting at the café.

    The ions and electrons must always arrive in step. If either path is blocked, the other stops too. That's why an open switch stops the lithium as well as the current.

    As the oxide fills up with lithium, its pull gets weaker, so the voltage slowly drops from about 4.2 volts to about 3 volts.

    Your phone's guard chip stops the battery at about 3 volts, even though there's a little lithium left, because draining further would damage the oxide.

Voltage
≈ 3.7 V
Phone uses
2–5 W

Did you know? A phone percentage isn't measured directly. The guard chip works it out from the voltage and by counting every bit of charge in and out.

Read more

Everything a battery does comes down to one thing: the lithium wants to be in the oxide more than in the graphite.

But the lithium can only move if its electrons can move too. And the electrons can only get across through the wire, so the battery only empties when the phone lets them.

This is how all batteries work. Two materials with different pulls, a liquid that lets ions through, and an outside path that the electrons must use.

When all the lithium has crossed, the battery is flat. So how do we get it back?

Every second you scroll, billions of billions of lithium ions cross a gap a hundred times thinner than a hair.

Step 7 of 8 · The lithium shuttle

Pushing it back

Battery low. You plug the phone in. Now the charger takes over, and everything runs backwards.

The charger pushes electrons back into the graphite side. The lithium ions follow, leaving the oxide and swimming back between the graphite sheets.

  1. The charger pushes. Charging is the shuttle run in reverse. The charger pushes harder than the battery can push back, so it forces electrons the other way: out of the plus side and into the minus side, through the wire. Energy from the wall socket goes into moving the lithium back uphill, so it's ready to be used all over again. Like carrying the ball back to the top of the slide.

    The charger has to push a bit harder than the battery's own voltage, a little over 4 volts, or nothing would flow backwards.

    A wall charger turns the high voltage from the socket into the low voltage a phone needs. Your phone then controls exactly how much goes into the battery.

    Some energy is always lost as heat while charging. That's why phones and chargers get a little warm.

  2. Lithium follows. As electrons arrive on the graphite side, lithium ions are pulled out of the oxide to meet them. They swim back across the liquid, through the separator, and slot in between the graphite sheets again. Each ion picks up an electron and settles in. When the graphite is full of lithium again, the battery is charged. Like guests heading home once the lights come on.

    Nothing new goes into the battery when you charge it. The same lithium just goes back to the graphite side, for the hundredth or thousandth time.

    Charging is slower than you might think because lithium has to squeeze between the sheets. Push too fast and it piles up at the surface instead.

    That's why fast charging is fast at first, then slows down near the end. The last spots in the graphite are the hardest to fill.

  3. Why it can repeat. Nothing gets burned up. The graphite and the oxide are just holders: their sheets open a little to let lithium in and close a little as it leaves, but stay the same. Only the lithium moves. Because the holders hardly change, a lithium-ion battery can be charged and emptied hundreds of times before wearing out. Like a shelf you stack and unstack books on, every day.

    Older rechargeable batteries changed their materials completely each time. That wore them out faster and made them heavier.

    This rocking back and forth is why lithium-ion batteries are sometimes called 'rocking chair' batteries.

    Each full empty-and-refill is called a cycle. Charging from 50% to 100% twice counts as one cycle, not two.

Charge voltage
≈ 4.2–4.4 V
Fast to 50%
≈ 30 min

Did you know? Phones slow down charging after about 80% on purpose. The last bit of lithium squeezes into the graphite slowly, so rushing it does harm.

Read more

When you plug in, the charger becomes the pump that lifts the lithium back up the hill.

Your phone controls charging carefully. First it pushes as much current as it safely can, then it holds the voltage steady and lets the current drop as the battery fills.

That's why the first half of charging is quick and the last few percent take a while.

So if nothing gets used up, why does a two-year-old phone die sooner than a new one?

Every time you charge, you're pushing lithium uphill, the same few grams, again and again for years.

Step 8 of 8 · Getting older

Why batteries age

A shuttle that runs back and forth a thousand times won't stay perfect. Each trip leaves a tiny bit of wear.

Each charge, a little lithium gets trapped in a crust on the graphite and stops shuttling. Charging too fast or too hot can even grow sharp lithium spikes.

  1. A crust forms. Where the graphite meets the liquid, a thin crust forms, called the SEI. It actually protects the graphite, but making it uses up some lithium, and it slowly gets thicker with every charge. Lithium caught in the crust can't shuttle any more. Less lithium moving means fewer hours of use on a full charge. Like limescale building up inside a kettle.

    SEI stands for solid electrolyte interphase. It's made of bits of broken-down liquid stuck to the graphite surface.

    The first crust forms at the factory, on the battery's very first charge. That's planned, and the first few per cent of lithium are spent making it.

    Heat speeds up the crust growing. A phone left in a hot car ages much faster than one kept cool.

  2. Lithium spikes. If you charge very fast, or when the battery is very cold, lithium arrives quicker than it can slot into the graphite. Instead, it piles up on the surface as metal. Over time, the metal can grow into thin, branching spikes called dendrites. If a spike reaches through the separator to the other side, the battery shorts. Like a crowd at a door: if it can't get in fast, people pile up outside.

    Spikes were the reason early lithium-metal batteries caught fire. Parking lithium safely inside graphite was the fix that made phone batteries possible.

    Charging in the cold is risky because the lithium moves sluggishly. That's why phones limit charging when they're freezing.

    Good chargers watch the temperature and slow down just enough to keep lithium slotting in neatly.

  3. Heat is the enemy. Batteries hate heat. Warmth speeds up every unwanted side reaction inside. And if a battery shorts, it can heat itself up, which makes it hotter still, a runaway loop that can end in fire. That's why the separator shuts down near 130 °C, and why the guard chip cuts the power the instant it sees trouble. Like a snowball rolling downhill, getting bigger as it goes.

    This runaway heating is called thermal runaway. It's rare, roughly one in tens of millions of cells, but it's why airlines ask you to keep batteries in the cabin, not in checked bags.

    Most batteries are happiest at room temperature. Using them in the heat of summer sun, or charging under a pillow, ages them fastest.

    Many phones now offer to stop charging at 80% overnight. A battery that isn't kept completely full stays cooler and gentler inside.

After 500 cycles
≈ 80% left
Best kept
16–22 °C

Did you know? Many phones can pause charging at 80% overnight and finish just before you wake up. Spending less time completely full helps the battery last longer.

Read more

Batteries don't suddenly stop working. They lose a little capacity with every cycle, until one day the phone doesn't last the afternoon.

Apple says many iPhones keep about 80% of their capacity after 500 full cycles, and newer ones after about 1,000. That's roughly two to three years of daily use.

The simplest ways to help: keep your phone cool, avoid running it to 0% often, and don't leave it sitting at 100% in the heat.

Every one of those habits comes back to the same idea: keep the lithium shuttling gently, so as little as possible gets trapped along the way.

Your battery wears out because of lithium that gets lost along the way, not because anything gets used up.

CHEMISTRY · 4 MIN

How Does a Phone Battery Work?

How a lithium-ion battery stores and releases energy

Starting the 3D engine